There's far too many variables to be able to specify an exact combination of settings for every sim. We have no idea what time your sims get up and whether they are totally refreshed when they do so or just hungry or in a hurry to rush out to work but still tired. Nor do we know what they do all day long, different activities expend energy at different rates (do they watch tv and nap all day or are they professional athletes or martial artists?)

But regardless of your starting points, it's fine to adjust the settings in the directions you wish until you get the results you want.

Relative Motives subject the sims motive gains/decays to the changes Relativity makes to the game clock speed. If you leave all of them on False, then motives will gain/decay at the same rates as if your overall Relativity setting were 37. I would suggest changing them all to True, but you don't have to if you have a reason not to. Some of this is more art than science.

Motive Deltas are the adjusted rates applied on top of the Relative changes for the replenishment of motives when a sim is doing something that raises the motive levels. For Energy, that would be sleeping, napping, getting/giving a massage, drinking tea from the Olde Mill tea set (there aren't many energy-replenishing activities in this game). Values over 1 are faster replenishment, 1 itself is standard so no change, under 1 (fractions between 0 and 1) are slower.

Motive Decays are the adjusted rates applied on top of the Relative changes for the depletion of motives when a sim is doing something that lowers (uses up) the motive levels. For Energy that would be exercising, swimming, jogging, working out, fighting, making up (I mean woohooing), and really just being awake but of course these things use up energy at different rates themselves. Values over 1 are faster depletion, 1 itself is standard so no change, under 1 (fractions between 0 and 1) are slower. At 1.25, you are making your sims use their energy when they are awake 25% faster than standard.

I suggest making your motives all relative and change those 1.25s to 1s to get a good starting point. Or, again more art than science, you could leave things as they are but change the Motive Decay for Energy in particular in the other direction like 0.75. You will know if you've gone too far, your sims won't be tired at 1 am or they might spring out of bed at 3 am all refreshed every morning. Note these settings are going to apply to all sims in town so you don't want to customize them necessarily for one particular household and it's going to take possibly more than a sim day to see the full effects.

Uni is where even I have to gesture wildly and the screen and try all kinds of different values because Uni World sims' autonomy is so goofy. Don't know why I even try to make any sense out of things they do there, I never could on the others I went to school with myself so many years ago either (and I'm sure they never knew quite what to make of me either, but that's beside the point).